Journal of Luminescence is an interdisciplinary journal of research on excited state processes in condensed matter

Journal of Luminescence is an interdisciplinary journal of research on excited state processes in condensed matter

New research from CSUEB department of math and computer science accepted for publication

  • March 23, 2010 5:00am

Dr. Zhi-Ji Cao, affiliated with the department of mathematics and computer science of Cal State East Bay, recently had his research related to the interaction between 1-[p-(dimethylamino) benzoyl]-4’-phenyl-semicarbazide and Cu2+, accepted for publication by the  Journal of Luminescence.

A new compound, 1-[p-(dimethylamino)benzoyl]-4’-phenyl-semicarbazide (1) was synthesized and showed highly selective response to Cu2+ over other metal ions such as Pb2+, Mg2+, Fe2+, Co2+, Zn2+, Cd2+, Hg2+, Ni2+, Ca2+, Ag+, Na+, K+ and Li+. The control compound, 1-[p-(dimethylamino)benzoyl]-4-phenyl-thiosemicarbazide (2), showed different fluorescence spectral response to Cu2+. A 1:1 complex between Cu2+ and 1 was formed while 1:1 and 1:2 complexes between Cu2+ and 2 were formed. The binding model between the receptor (1 or 2) and Cu2+ was supported by IR spectra, mass spectra and computation model. 1 possessed higher selectivity towards Cu2+ compared with 2 owing to the difference of complexation ability between urea and thiourea groups.

CSUEB faculty, staff and students by access the full article online through the library.

California State University, East Bay is the San Francisco East Bay Area's high-access public university of choice. CSUEB serves the region with campuses in Hayward and Concord, a professional development center in Oakland, and an innovative online campus. With an enrollment of more than 14,000, the University offers a nationally recognized freshman year experience, award-winning curriculum, personalized instruction, and expert faculty. Students choose from among more than 100 professionally focused fields of study for which the University confers bachelor's and master's degrees, as well as an Ed.D. in education. Named a "Best in the West" college, as well as a Best Business School, by the influential Princeton Review, Cal State East Bay is among the region's foremost producers of teachers, business professionals and entrepreneurs, public administrators, health professionals, literary and performing artists, and science and math graduates.

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